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Sherborne and Claeyssens

Ref [61] [57] [87] [64] [65] [67] [66] [24] [68] [69] [70,71] [73] [72] [74] [82] [27] [29]

Characteristics High thermal resistance Heparin functionalized to purify Enterovirus 71 (EV71) Kaolin-loaded, 3D-printed cure on dispense 3D printed Surface epoxy groups can be chemically modified Flexible polyHIPE membranes that can be rolled into a module Proteins recovery with no obvious sign of unfolding High column efficiency and protein-binding capacity Redox-initiated polymerization for in situ polymerization of a filter Made using r

functionalization Amino (–NH2) Modified to bear weak anion exchange groups Surface functionalized to create weak anion exchange supports Anion exchange functionality using Surface modified by Air oxidation produces hydroperoxide species Sulfonated to produce hydrophilic surface In situ functionalization using sodium acrylate amphiphilic block copolymers for potential surface functionalization

Surface functionalized Heparin - iodomethane diethylamine - - - - Stabilized with - -

Interconnect (μm) 1.1–2.4 0.2–0.5 ≈0.75 0.1–0.5 1 – 3 - - 2.4–6.4 7.8–13.5 - - - 0.19–0.59 0.1–3 1–5 0.2–5.9 - The monomer abbreviations used are: MMA, methyl methacrylate; EGDMA, ethylene glycol dimethacrylate, DVB, divinylbenzene; GMA, glycidyl methacrylate; EHA, ethylhexyl acrylate; BeMA, benzyl methacrylate, TEOS, tetraethyl orthosilicate; St, styrene; DCPD, dicyclopentadiene, P4VP, polyvinylpyridine; PEG, polyethylene glycol; SA, so

Pore size (μm) 3.0–7.4 0.5–2 ≈3 1–10 3 – 10 - 0.6–0.1 16–29 82.3–145.6 - 1–4 23.9±16.4 - 1.08–1.12 1–80 5–50 0.8–25 and 0.6–4.5 1.6–9.3

Column to purify virus for 3D-printed hemostatic and absorbent polyHIPE wound Protein separation through Protein purification by Protein separation by In situ cured open pored Decontamination of chemical warfare agent and self- decontaminating air filter Chromatographic separation Ultrafiltration of microalgae Bacteria filter and its inactivation using NIR Improved mechanical properties of polyHIPE

Application Air filter vaccine production dressing chromatography chromatography Ion exchange chromatography chromatography filter Oil recovery Oil spill recovery Microfiltration of nanoparticles sterilization Ultra-low-density polyHIPE

Table 2. PolyHIPE filter-based applications Poly(St-MMA-DVB) Poly(St-GMA-DVB) PEGMA-SA-PEGDA Poly(GMA -EGDMA) Poly(GMA -EGDMA-EHA) Epoxy resin-based monolith with GMA brushes Poly(GMA -co-EGDMA) Poly(MMA-co-EGDMA) and poly(BeMa-co-EGDMA) Sulfonated polystyrene, EGDMA, TEOS, and butyl acrylate Poly(St-DVB) with EHA or ethyl vinyl benzene Poly(St-DVB) and poly(EGDMA) Poly(butyl acrylate- EGDMA) Poly(St-b -P4VP) Poly(MMA-EGDMA) PEGMA, polye

Poly(St-DVB)
Poly(DCPD)

Material International Journal of Bioprinting (2021)–Volume 7, Issue 1 Poly(St-DVB) 53