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Materials Science in Additive Manufacturing                              High-performance materials in AM



                                                               this technology build complex 3D structures by spraying a
                                                               photosensitive liquid material layer by layer over a specified
                                                               area with a nozzle and curing it with ultraviolet light.
                                                                 This  technology  offers  high  cost-efficiency  and
                                                               application potential. In addition to being suitable for
                                                               traditional thermoset photopolymers, MJT has shown
                                                               adaptability to a variety of materials such as gels and bio-
                                                               based materials . It has also received increasing interest
                                                                           [30]
                                                               from the market as well as industry in recent years because
            Figure 4. Illustration of material extrusion with or without cells   it can be used in informal settings such as office scenarios
            (permission obtained from authors) .               due to its similar working characteristics to traditional
                                   [25]
                                                               printers . On the other hand, the ability to print
                                                                     [29]
              One of the advantages of MEX technology is that it is   simultaneously with multiple materials is a major advantage
            inherently less restrictive in terms of raw materials. Most   of MJT technology. The high dimensional accuracy and
            of the feedstocks are very inexpensive, and a considerable   low surface roughness of the finished products fabricated
            proportion of the model material is open source, reducing   using MJT technology make it potentially useful in areas
            the cost of learning for the user themselves, and making   such as cutting-edge customized medicine, aerospace, and
            it highly adaptable and relevant for the home market.   other applications .
                                                                             [31]
            At the same time, 3D printers using MEX technology   The current shortcomings of MJT technology
            are generally less expensive to maintain and run and are   are divided into two principal areas: material and
            therefore used in some commercial scenarios to produce   technology. The layer-by-layer method has gaps and
            prototypes.
                                                               defects that can have a significant impact on the final
              On the other hand, there are limitations to the strength   performance of certain elastomeric materials, such as
            of the finished products printed by MEX technology,   fatigue life [32] ; on the other hand, the raw materials used
            especially for the perpendicular Z-axis direction (along the   in MJT technology are photosensitive, the mechanical
            build direction), where there is a large deficit in strength.   properties of the finished product could potentially
            At the same time, if the user tries to increase the accuracy   deteriorate over time [33] .
            of a 3D printer using MEX technology, the corresponding   Targeted research has been followed up. By studying the
            fabrication time increases, which limits the value of this   aging of different color resins printed by MJT over time,
            technology to a certain extent.
                                                               the researchers found that the stiffness of the material
              Most importantly, the thermoplastic material in a MEX   first increased and then decreased over time, and the
            process can be heated to a maximum of 500°C, thereby   aging process has a potential relationship with the color
            emitting harmful gases and ultrafine particles that can lead   and appearance of the product itself . At the same time,
                                                                                            [34]
            to a reduction in indoor air quality in domestic scenarios.   various tests were carried out; the structure of the whole
            This poses a potential health problem for the occupants of   experiment is shown in Figure 5.
            the house, considering that some components take more   These studies provided the basis for understanding the
            than a few hours to fabricate .
                                  [27]
                                                               long-term factors affecting the changes in the appearance
              It is worth noting that MEX technology may be    and performance of objects printed using MJT technology.
            developed for medical applications because it is compatible   In the future, on this basis, through a series of research on
            with most materials. This certainly broadens the potential   the parameters of the entire industry chain and product
            market for this easy-to-use technology. Recent studies   design, it may be possible to greatly increase the lifespan
            have successfully used medical-grade polyamide (PA)12   of the product and enhance the actual application value of
            polymer as matrix material to complete the print; it was   the technology.
            also found that by adding silver nitrate, polyethylene
            glycol or polyvinylpyrrolidone, the printed samples could   2.5. Powder bed fusion
            further exhibit higher tensile strength or sterilization   Powder bed fusion (PBF) technology is an important
            properties .                                       branch of AM. Especially in the field of metal additive
                    [28]
                                                               manufacturing, PBF occupies an absolute advantageous
            2.4. Material jetting                              position.  Figure 6 illustrates the market share held
            MJT  technology is  an  AM  technology  that  is  somewhat   by different technologies in the metal additive
            similar to conventional 2D printers . 3D printers using   manufacturing segment in 2019 [17] . PBF technology, as
                                         [29]

            Volume 2 Issue 3 (2023)                         4                       https://doi.org/10.36922/msam.1587
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