Page 60 - IJB-5-1
P. 60

Mechanisms and modeling of electrohydrodynamic phenomena
                                                                                        2
           parameters  are given .  According  to  data  obtained   hydrodynamic time is  t =  lD n . The characteristic flow
                              [18]
           from experiments, Cloupeau and Prunet found that the          γε ε     h    Q              V
           cone-jet mode only appears at a certain range of voltage   rate is  Q =  ρ 0  r , characteristic distance   05 .   and
                                                                      0
           and  flow  rate,  and  instabilities  including  skewed  and    K           ε 0 05.  .   γ   D 
                                                                                                      0
                                                                                                       
           multiple-jet regime appear in a larger electric field . At   characteristic current  I = γ ( ρ  )    ε 0 
                                                     [57]
                                                                                  0
           specific  conditions,  operating  diagram of cone-jet  can   These dimensionless groups have a certain influence
           be  described  as  changes  of  flow  rate  and  electric  field   on jet diameter and current, qualitatively. In the classical
           strength [5,57] . Domains of cone-jet may become different   EHD jetting system, the charge relaxation time is smaller
           by small changes in the selection of parameters mentioned   than  the  hydrodynamic  time (t <t );  most  of EHD
           above (such as working fluid, setup of the experiment,   printing,  electrospray, and electrospinning  belong  to
                                                                                              h
                                                                                            e
           and geometry of nozzle). Furthermore, experimental   this category . Charges are induced toward the surface
                                                                         [33]
           measurements are also difficult for the flow fields in a   of the liquid to form a thin layer of charge under the
           free jet whose diameter is often on the verge of optical   liquid-gas interface , and both the shape of the liquid
                                                                               [33]
           resolution .                                        cone and the jet stability are affected by the amount of
                   [5]
                                                                                             [38]
           3.2.1 Dimensional Analysis                          electric charge on the liquid surface . For liquids with
                                                               relatively  high conductivities (above  10  S/m), the
                                                                                                   −4
           In this section, the effect of parameters on the transition   electrical  relaxation  time  is  short  and  sufficient  charge
           process is reviewed. The cone-jet transition is confined to   can accumulate on the surface to counteract the surface
           the region near the conical apex. First, the dimensional   tension force . The jet formation zone is limited to the
                                                                          [38]
           analysis is used to give a qualitative description of the jet   apex of the conical meniscus . The remaining surface is
                                                                                       [57]
           diameter, D , and emitted current, I j [38] . The jet diameter and   practically equipotential, and an almost static equilibrium
                    j
           current are related to the operating parameters (flow rate   of forces exists at each point . The shape of the cone
                                                                                        [57]
           Q and electric field strength E), liquid material properties   may have a practically straight generatrix with a very fine
           (density  ρ,  viscosity  μ,  electrical  conductivity  K,  gas-  jet (Figure 3A) or exhibit a shape as in Figure 3B . In
                                                                                                         [18]
           liquid surface tension γ, and fluid relative permittivity ε ),   Figure 3C and D, the acceleration zone extends further
                                                         r
           and geometrical  parameters  (nozzle  diameter  D  and   toward the base of the cone and the profile of liquid has a
                                                      n
           distance  between  two  electrodes  H).  If  parameters  ρ,   similar shape of cone-jet with an open cone for decreasing
           γ,  K,  and  the  va`cuum  permittivity,  ε , are  selected  as   conductivities . Flow rate required for stable cone-jet
                                                                          [57]
                                            0
           dimensionally  independent  variables  in this functional   mode moves toward a lower threshold with an increase in
           relation for the jet diameter and current, dimensions of   conductivity when all other parameters are kept same .
                                                                                                            [57]
           these related variable are [ρ] =ML , [γ] = MT , [K] =   In the non-classical EHD (t >t ), there is insufficient time
                                        −3
                                                   −2
                                                                                     e
                                                                                        h
           MLT V , and . Next, the Buckingham’s Π theorem can   to develop an appreciable surface charge, and electrically
               −3
                  −2
           be applied to perform a dimensional analysis [38,55] :  forced jet may appear, like a ball cone-jet [33,58,59] . Although
                                                             it is not possible to obtain very fine jets with liquid of low
                                                             conductivity unless special methods are used , it is still
                                                                                                    [57]
                D      Q      V       ρ Q  D    l
                 j  =  f    ,     , ,   0  ,  n  ,    (5)    possible to produce a jet for liquids with low electrical
                                   ε
               D 0      Q 0 γ D   05 .  r  µ D 0  D 0  D 0     conductivities (10  S/m) . The conical shape ultimately
                                                                             −13
                                                                                    [58]
                              0
                                                                                                            [57]
                            ε 0                        disappears when the liquid has a very low conductivity .
                                                               Electrical stress cannot counteract the surface tension to
                                                               deform the meniscus into a cone, and the pendant droplet
                                                             grows in volume and finally drips off.
                                                               In the experiment of Juraschek and Rollgen, both
                I                    ρ Q  D    l
                j  =  g   Q  ,  V  ε  ,  0  ,  n  ,    (6)
               I 0      Q 0 γ D  05 .  r  µ D 0  D  0  D 0     A                   C
                             0
                           ε 0                                     B                          D
             Where  f()  and  g()  are  dimensionless  functions.
           Lee  et al. add a ratio  of two characteristic  times,  t /t ,
                                                        e h
           where t  is charge relaxation  time,  which is the
                  e
           characteristic time of charge transport determined by the
           electrical properties of the fluid, and t  is hydrodynamic
                                           h
           time,  which  is  the  characteristic  time  of  the  fluid   Figure 3. (A-D)  Different forms of the meniscus in cone-jet
           supply [33,55] . The charge relaxation time is  t =   r  and   mode .  Adapted  by permission  from  Michel  Cloupeau  et  al.
                                                                   [57]
                                                    0
                                                e
                                                    K          (1989) under the Elsevier.
           6                           International Journal of Bioprinting (2019)–Volume 5, Issue 1
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