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31    INNOSC Theranostics and Pharmacological Sciences, 2023, Vol. 6, No. 1                       Sinha
           utilized after the date of expiry, it adversely affects   might end up choosing these cements due to their
           the bond strength [27]. Unhydrolyzed form of         simplicity and lower potential in application error.
           silanes or inactive silanes was two-bottle systems   However,  in vitro investigation  of these cements
           utilized by the clinicians. Mixing of the ingredients   showed that  they bond to the dentin and enamel
           is done before application, ensuring a more active   lesser than the effect demonstrated by the adhesive
           form with a longer shelf life [28,29].               system and resin cement [33,34].

           5.1.1.2. Etching system                              5.2. Particle-filled glass ceramic

           Adhesive cementation process for dentin or the       This form of ceramic consists of several amounts,
           enamel necessitates the adhesive system use,         particle  types, and glassy matrix.  The particles
           followed by the resin cement application [4].        inclusion has helped in improving the physical
           The adhesive systems can be either a self-etching    strength  of ceramic.  Reduction  in  the  amount  of
           system or a total etching system.  Among these       glass and increase in the number of particles leads to
           two-adhesive  systems,  self-etching  system  is  the   increase in the strength of material. However, some
           popular one among the dental surgeons as it is       esthetic and translucent properties are diminished
           easier to use.                                       due to this process. Based on its strength, several
                                                                materials  in the  category  can  be utilized  as the
           5.1.1.3. Resin cement                                copings or veneering material [2].

           It is also vital to strictly follow the instructions   5.2.1. Low-filled material
           provided by the manufacturers during the adhesive
           cementation  process, including  the use of the      Low-filled  material  such  as  ordinary  Portland
           resin cement and adhesive combination  of the        cement (OPC) (“Jeneric Pentron,  Wallingford,
           manufacturers,  as the  researchers  found certain   Conn”) and IPS Empress Esthetic (“Ivoclar
           incompatibilities between the simplified adhesive    Vivadent”)  has  been  filled  with  the  leucite.  The
           system and dual cure resin cement [30,31].           physical strength of these materials has been
              Resin cements are usually polymerized through     relatively  lower  when  compared  to  other  filled
           chemicals,  light or a process combining both        glass material.  This is one of the major reasons
           light  and chemicals.  Light-polymerized  resin      why these materials were indicated mainly for
           is  recommended  when  a  thin  and  translucent     the veneers, outlays, and inlays and lower stress
           ceramic  is available.  This is because it allows    situations [3].  These forms of ceramics should
           the light transmission through itself for reaching   be adhesively cemented for improving their
           resin cement.  In contrast to light-polymerized      strength [20].  The procedure of cementation is
           resin, dual-polymerized resin cement is indicated    almost similar to the procedure described for
           whenever the ceramic has been too opaque or too      predominantly glass ceramic.
           thick to enable light transmission through it [17].   5.2.2. Intermediate-filled material
           Finally, polymerized resin cement with chemicals
           does not offer selection in terms of translucency or   Intermediate-filled  material  such  as  OPC  3G
           shade. Hence, the dual-polymerized resin cement is   (“Jeneric Pentron”) and IPS e-max Press (“Ivoclar
           considered to be the most beneficial. In addition, the   Vivadent”) has been reinforced with the lithium
           accessible areas might benefit from the use of light   disilicate,  and it  has enough  strength  and good
           polymerization  along  with the  dual-polymerized    esthetic properties, which are sufficient to allow the
           resin cement [32].                                   use of this material for the single crown, veneers,
              A self-adhesive resin cement has been introduced   and copings.  These materials  can be cemented
           to reduce the steps in bonding and also enhance the   either  adhesively  or non-adhesively, when it is
           ease of use. Such approach helps in combining the    utilized for the full-coverage restorations. Research
           cement and adhesive in a single step. Using a self-  studies have been reporting that there  have been
           etching primer before the application  of cement     no  significant  differences  between  both  types  of
           is another approach developed.  Dental surgeons      cementations [35,36].

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