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Materials Science in Additive Manufacturing                         Preparation and modification of porous Ti




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            Figure 8. Different metal additive manufacturing processes. (A) Schematic diagram depicting the principle of preparation by laser selective melting.
            (B) Schematic diagram depicting the of processing principle of electron beam melting.  (C) Schematic diagram of direct writing ink technology. 67
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            3.3.2. Direct ink writing technology               TC4 porous scaffold with 50% porosity was obtained after
                                                               sintering, and its maximum compressive and buckling
              Direct  ink  writing  technology  is  a  new  additive
            manufacturing molding process in which a suspension is   strengths were 60.47 and 106.8 MPa, respectively.
            prepared by mixing a metal powder material with a viscous   Compared with SLM and other technologies, DIW
            fluid before printing. The suspension is then loaded into a   technology avoids the temperature gradient caused
            printer and extruded through a nozzle for molding, and   by laser and other heat sources and effectively reduces
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            the extruded material is dried and sintered to form a 3D   internal stress concentration, cracks, and other defects.  It
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            porous structure,  as shown in Figure 8C.          can carry bio-friendly elements or drugs and has excellent
                                                               potential in targeted therapy and osteogenic induction.
              Zhao et al.  prepared porous Ta-Ti-Nb-Zr high-entropy   However, this method is still fraught with problems of a
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            alloy using DIW technology. By adjusting Zr content,   single structure and low strength. 85
            porous  titanium  alloys  with  different  properties  were
            obtained, whose compressive strength increased from   Table 1 summarizes the advantages and disadvantages
            70.08 to 149.95 MPa, and elastic modulus increased from   of different preparation processes for medical porous
            0.18 GPa to 0.64 GPa. To improve the molding accuracy   titanium scaffolds. The structural parameters and
            of extruded materials, Li et al.  designed a photocurable-  performance of porous titanium scaffolds prepared by
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            assisted technology to print porous Ti6Al4V alloys by   different processes are summarized in Table 2.
            DIW. Titanium alloy suspension with a powder content   4. Surface modification method of porous
            of 45% was prepared based on 1,6-hexanediol diacrylate
            monomer and trimethylolpropane triacrylate monomer   titanium alloy
            (HDDA-TMPTA) photosensitive system. The extruded   The advances attained in porous titanium alloy, which
            suspension  was  cured  by  ultraviolet  irradiation,  and  the   has significantly reduced elastic modulus and improved


            Volume 3 Issue 1 (2024)                         10                      https://doi.org/10.36922/msam.2753
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