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International Journal of Bioprinting                            Corrosion behavior of SLM-prepared 316L steel




            1. Introduction                                    directed energy deposition (DED)-based AM methods
                                                               on the microstructures and mechanical properties of the
            Additive  manufacturing  (AM),  usually  referred  to   316L steel. Guo et al. , who used the high-power direct
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            as three-dimensional (3D) printing, involves several   laser  deposition  (HP  DLD)  method,  reported  that  the
            technologies, such as powder bed fusion (PBF), which   microstructures and properties depended significantly on
            comprises selective laser melting (SLM)  and direct metal   the building direction. Regarding the optimized processing
                                            1
            laser sintering (DMLS).  The technologies are utilized   parameters, the therein achieved ultimate tensile strength
                                2
            based on a computer-generated model to fabricate a 3D   (UTS) reached 900 MPa. Yin  et al.  documented that
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            product.  Contrary to the conventional manufacturing   the  thermal  stability  of  the  microstructures  as-built  by
                   3
            methods, such as rolling, forging, extrusion, or drawing,   laser powder bed fusion (L-PBF) lasted for up to 400 h
            AM technologies create the materials monolithically in   between 500°C and 600°C, and decreased significantly
            a layer-by-layer fashion. The technologies are suitable to   with increasing the temperature to 800°C. As the
            fabricate  tailored  components  with  complex  geometries   microstructures and possible presence of printing defects
            from various metals,  polymers,  and also ceramics.    also affect the lifetime of the components, several research
                                                         7,8
                             4,5
                                        6
            Over the recent years, AM has demonstrated success in   groups have examined the fatigue properties of AISI 316
            fabrication of intricate components applicable in a variety   steel prepared by AM 32-34  and compared the results with
            of industrial fields, including aerospace, automotive, or   those acquired for conventionally prepared steels 35,36 ; such
            biomedicine. For example, AM has already been used   comparisons were also performed from the viewpoints of
            to fabricate complex bio-applicable structures, such as   machinability 37,38 . Interestingly, Vinoth et al.  reported that
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            scaffolds, and patient-specific implants. 9-11
                                                               the wire arc additive manufacturing (WAAM) method can
               Despite its indisputable advantage, i.e., the ability to   be used to fabricate steel plates that exhibit open pores after
            create tailor-made geometries, AM also features several   machining, which could be beneficial for a prospective
            disadvantages, including residual porosity, surface   bio-application.
            roughness, inhomogeneous distribution of residual stress,   The 316L steel is one of the most commonly used,
            and possible distortion of  the  final components 12,13 .  In   affordable materials for fabrication of various implants
            order to eliminate the printing defects, post-processing via   used in human body . Examining the corrosion behavior
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            a heat treatment, possibly combined with a high pressure   of a bio-applicable material is of high importance because
            (such as during the hot isostatic pressing [HIP] method) ,   corrosion not only decreases the lifetime of the implant,
                                                         14
            or processing via plastic deformation , has been proven   but it also triggers release of ions from the implant
                                          15
            to be advantageous. Besides, optimized deformation   materials, which can (negatively) affect the surrounding
            (thermomechanical) treatment has been shown to also   living tissues and cause inflammatory or anaphylactic
            favorably enhance the mechanical properties of AM-  responses 27,41 . Shih et al.  documented that wrought 316L
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            prepared materials (steels) 15-17 .                steel components are prone to exhibit localized corrosion
               The  AISI  316L  stainless  steel  is  widely  applicable  in   and would gradually become cytotoxic as a result of the
            numerous commercial and industrial fields, from chemical   corrosion reactions. Majumdar  et al.  reported that
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            and petrochemical industry , through nuclear energetics ,   almost 50% of 316L steel implantation failure is related
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                                  18
            transportation and marine 20,21 , to food industry and   to corrosion. To address this problem, various types of
            biomedicine 22,23 . Given its versatility, it has been the focus   coatings (e.g., ZnO and TiO  films) and surface treatments
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            of numerous researchers working on the optimization of   have been introduced to decrease the corrosion rate of the
            its production technologies and preparation processes. Its   stainless steel 43-45 . As the corrosion behavior is dependent
            manufacturability by conventional production methods, as   not  only on  the  chemical composition  of  the material,
            well as by modern and unconventional methods, such as   but also on the microstructure and intrinsic properties,
            hydroforming, electroforming, or severe plastic deformation   studies on AM-prepared 316L steel have been performed
            (SPD) techniques, has been proven 24-26 . Recently, the 316L   as well. Upon comparing the corrosion behaviors of 316L
            steel has also been gaining traction among researchers   steel samples prepared conventionally and by AM+HIP
            and manufacturers dealing with AM technologies 27,28 . As   in H SO  and HCl solutions, Fredriksson  et  al.  found
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            the  selected processing parameters and particular AM   that the AM+HIP sample exhibited better resistance to
            technology directly influence the acquired microstructures   pitting corrosion due to the formation of a thicker passive
            and thus the mechanical properties, investigating the   layer. The application of HIP has been shown to favorably
            correlation of these variables has always been the main   enhance the corrosion resistance of AM-prepared steels .
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            goal of numerous studies. Saboori  et  al.  reviewed and   However, HIP alone is not able to fully eliminate residual
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            summarized the effects of processing parameters of   porosity, which tends to increase both the corrosion rate
            Volume 10 Issue 1 (2024)                       340                          https://doi.org/10.36922/ijb.1416
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