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Materials Science in Additive Manufacturing                      Laser absorption and printability of 90W-Ni-Fe


                                                               the above discussion and results, several conclusions can
                                                               be drawn:
                                                               (i)  It was discovered that the morphology of nanoparticle-
                                                                  coated  90W-Ni-Fe  powder  prepared  by  different
                                                                  milling conditions was different; this was attributed
                                                                  to the difference in milling energy caused by different
                                                                  milling parameters. Reinforced particles were
                                                                  gradually dispersed uniformly with increased specific
                                                                  impact energy in ball milling, but particle deformation
                                                                  and breakage were more likely to occur.
                                                               (ii)  Powder morphology was optimized to obtain stable
                                                                  laser absorption behavior with high absorptivity in
                                                                  both horizontal and vertical directions of the powder
                                                                  bed. Homogeneous nanoparticle-coated 90W-Ni-Fe
            Figure  14.  Compressive stress-strain curve of LPBF-processed part   powder with good sphericity had the best laser
            fabricated by optimized nanoparticle-coated 90W-Ni-Fe powder.  absorption behavior. Agglomerated nanoparticles
                                                                  made laser beams reflect between nanoparticles and
            A                      B                              reduced the stability of laser absorption behavior.
                                                                  Deformed  matrix  particles  weakened  the  multiple
                                                                  reflections and lowered laser absorptivity and
                                                                  penetration.
                                                               (iii) Laser absorption of nanoparticle-coated 90W-Ni-Fe
                                                                  powder with different morphologies was different,
                                                                  thus making their LPBF printability different.
            Figure 15. Microstructures of LPBF-processed W (A) and W-Ni-Fe (B)   Homogeneous  nanoparticle-coated  90W-Ni-Fe
            specimens.                                            powder  with  good  sphericity  had  the  best  LPBF
                                                                  printability with a straight scanning track free of
            improvement of compressive strength was attributed to   balling effects, which had a good agreement with
            the transformation of the microstructure from columnar   modeling results.
            to equiaxial grains when the Ni and Fe nanoparticles were   (iv)  The 90W-Ni-Fe alloys fabricated by optimized powder
            added to the W matrix. As the surfaces of W particles were   had the best surface quality (surface roughness of
            coated with Ni and Fe, the continuous growth of W grains   7.91   μm), the highest densification level (density
            was prevented and the growth of the equiaxial grains   of 98%), and uniform residual stress distribution.
            was promoted instead. Meanwhile, the nanoparticles    Moreover, the 90W-Ni-Fe alloys had a uniform hardness
            were diffused to the grain boundaries due to their strong   distribution with an average value of 439.47 HV , and
                                                                                                         1
            activity, reducing the microcracks and resultant grain   they had better compression properties (compressive
            boundary strengthening. The microstructures directly   strength of 1255.35 MPa with an elongation of 24.74%)
            determined the mechanical properties of the final parts,   compared with LPBF-processed pure W parts.
            thereby improving the mechanical properties of LPBF-  Acknowledgments
            fabricated W-Ni-Fe alloys.
                                                               None.
            4. Conclusion
                                                               Funding
            Through numerical and experimental investigations,
            this study examined the effects of nanoparticle-coated   This work was supported by the Science Challenge Project
            90W-Ni-Fe powder morphology on the laser absorption   (No. TZ2018006-0301-02 and No. TZ2018006-0303-03),
            behavior and the printing quality of LPBF. GO-RT models   National Natural Science Foundation of China for Creative
                                                                                                       th
            and CFD-PM models were first established to obtain an   Research Groups (Grant No.  51921003), The 15   Batch
            in-depth understanding of mechanisms during LPBF   of “Six Talents Peaks” Innovative Talents Team Program
            fabrication of W-based alloys. Nanoparticle-coated   (No. TD-GDZB-001), The Fundamental Research Funds
            90W-Ni-Fe powders were prepared and corresponding   for the Central Universities (NO. NC2020004), and Basic
            alloys were fabricated by a self-developed device. Based on   Strengthening Program (No. 2019-JCJQ-JJ-331).


            Volume 1 Issue 2 (2022)                         11                     http://doi.org/10.18063/msam.v1i2.11
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