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Materials Science in

                                                                  Additive Manufacturing



                                        ORIGINAL RESEARCH ARTICLE
                                        An exploratory study on biocompatible

                                        Ti-6Mn-4Mo alloy manufactured by directed
                                        energy deposition



                                        Roman Savinov , Yachao Wang , and Jing Shi *
                                                     1
                                                                               1
                                                                   2
                                        1 Department of Mechanical and Materials Engineering, University of Cincinnati, Cincinnati, Ohio,
                                        United States of America
                                        2 Department of Mechanical Engineering, University of North Dakota, Grand Forks, North Dakota,
                                        United States of America



                                        Abstract

                                        Titanium is a widely used metal in biomedical applications due to its low toxicity, but its
                                        mechanical properties need to be tailored for different applications. Efforts are called
                                        for to search for effective and yet non-toxic elements to be alloyed with Ti to improve
                                        its strength. Fitting in this category, Mn and Mo are two such alloying elements. In
                                        this study, Ti-6Mn-4Mo alloy was manufactured by laser-directed energy deposition
                                        (DED) through in situ alloying of Ti, Mn, and Mo elemental powders. This study was
                                        intended to not only demonstrate for the first time the printability of the Ti-Mn-Mo
                                        ternary system by laser DED but also investigate the basic mechanical properties
                                        and corrosion resistance of the obtained alloy. Under the as-built condition, the alloy
                                        consisted mainly of ß phase, while after heat treatment it was transformed into α
            *Corresponding author:      phase. The average ultimate tensile strength under as-built condition was 706.0 MPa,
            Jing Shi
            (jing.shi@uc.edu)           lower than similar alloys from conventional methods. However, the average hardness
                                        reached 421.1 HV for the as-built condition, much higher than the similar alloys made
            Citation: Savinov R, Wang Y,   through conventional methods. On the other hand, the corrosion resistance of the
            Shi J, 2023, An exploratory study
            on biocompatible Ti-6Mn-4Mo alloy   obtained alloy was found to be relatively low compared to similar alloys produced
            manufactured by directed energy   with traditional methods. In addition, heat treatment was not able to significantly
            deposition. Mater Sci Add Manuf,   change the tensile properties or the corrosion resistance. In essence, the exploratory
            2(4): 2180.
            https://doi.org/10.36922/msam.2180   study indicates that the DED-produced Ti-Mn-Mo alloy could be deposited without
                                        cracks and major voids, and shows that its high hardness and modulus are attractive
            Received: November 6, 2023
                                        to applications for high wear resistance. However, further investigation is needed to
            Accepted: November 24, 2023  improve strength, ductility, and corrosion resistance of the alloy.
            Published Online: December 8,
            2023
                                        Keywords: Ti-Mn-Mo alloys; Laser-directed energy deposition; Tensile properties;
            Copyright: © 2023 Author(s).   Hardness; In situ alloying
            This is an Open-Access article
            distributed under the terms of the
            Creative Commons Attribution
            License, permitting distribution,
            and reproduction in any medium,   1. Introduction
            provided the original work is
            properly cited.             To be suited for biomedical applications, metal alloys should possess certain properties.
            Publisher’s Note: AccScience   The alloys should be nontoxic, non-carcinogenic, and ideally highly resistant to wear
            Publishing remains neutral with   and corrosion. To date, the most used metallic biomaterials have been stainless steels,
            regard to jurisdictional claims in                    [1]
            published maps and institutional   Co-Cr alloys, and Ti-based alloys . Stainless steels are often used due to their corrosion
            affiliations.               resistance and relatively low price. Co-Cr alloys are hard and wear-resistant metals and


            Volume 2 Issue 4 (2023)                         1                       https://doi.org/10.36922/msam.2180
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