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Materials Science in Additive Manufacturing                                   Directed energy deposition




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            Figure 7. Microstructure and elemental distribution of (A) H-DED and (B) B-DED coating sub-surface. Red numbers indicate the points for chemical
            composition analysis. Scale bars: 2.5 μm
            Abbreviations: B-DED: Broad-beam laser-directed energy deposition; H-DED: High-speed directed energy deposition


            Table 2. Chemical compositions of the H‑DED and B‑DED coatings  that these oxides act as lubricants between the specimen
            Coating  Point          Elements (wt.%)            and the friction pair, reducing the friction coefficient and
                          Fe   Cr  C   Ni  Si  Mo   P   S      improving  wear  resistance.  The  average oxygen content
                                                               on the worn surfaces of the specimens is 9.91 wt.% (DI),
            H-DED     1   62.2  22.6  6.4  7.0  0.8  0.8  0.1  0.1
                                                               26.4 wt.% (H-DED), and 13.2 wt.% (B-DED), which
                      2   66.2  18.9  3.9  8.9  1.1  0.9  0.1  0.0  corresponds with the wear resistance trend observed in
            B-DED     3   64.4  22.3  7.1  4.2  0.7  1.2  0.1  0.0  Figure 9.
                      4   77.3  11.4  2.6  7.2  1.4  0.0  0.0  0.1  In  Figure  10A   and  A , rows  of grooves along the
                                                                              1
                                                                                     2
            Abbreviations: B-DED: Broad-beam laser-directed energy deposition;   sliding direction can be observed, a typical characteristic of
            H-DED: High-speed directed energy deposition.
                                                               abrasive wear. This is primarily due to spheroidal graphite
                                                               spalling during the wear process of the DI specimen,
            in  the  DI  specimen  act  as  a  third-body  abrasive  during   forming a third body between the friction pair and the
            wear, reducing the friction coefficient. 2,35      worn surface. Therefore, the wear mechanism of the DI
              Figure  10  displays the localized wear morphology   specimen is mainly characterized by three-body abrasive
            and elemental distribution of the coatings and substrates.   wear. The spalled graphite can absorb normal stress and
            Prolonged and intense friction resulted in varying degrees   grind  the  spalled  material  into  finer  debris,  thereby
            of oxidation on the surfaces of all specimens, as indicated   reducing friction and improving wear resistance. However,
            by the oxygen distribution maps. Studies 24,28  have reported   the resulting voids are prone to stress concentration, leading

            Volume 3 Issue 4 (2024)                         7                              doi: 10.36922/msam.4974
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