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Materials Science in Additive Manufacturing                               3D printing of anti-microbial parts



            (Figure  S3),  there  would  be  no  such  surface  renewal  in   tensile strength compared with IM parts, possibly due to
            everyday  use. In this  regard, dead bacteria may form  a   the sintering method leaving about 2 vol.% voids, even
            biofilm, allowing new bacteria to deposit on the debris.   when the best polymers are used for the process 30,24 .
            This can lead to gene transfer from the dead bacteria to the   Adding rigid inorganic crystals to the surface might
            living ones. Hence, the surface has to be wiped or hosed   embrittle the article further and make it unusable. Hence,
            to regenerate the activity. From an application perspective,   PA 12 tensile bars were printed by HSS and dip-coated
            this work highlights that Mg(OH)  NPs are effectively   with Mg(OH) crystals, and the tensile properties were
                                         2
            embedded in HSS-printed articles, allowing for cleaning   measured.  2
            and reuse. It is also possible that if the HSS-printed articles
            are steam-sterilized (a common hospital procedure for   The  tensile  properties  for  the  various  HSS PA  12
            reusable articles), the dead bacteria would be removed and   bars before and after coating with Mg(OH) crystals
                                                                                                      2
            the surface regenerated for anti-microbial protection.  are presented in Figure  13. While there is a decrease in
                                                               the tensile properties after coating, the reduction is not
            3.6. Evaluation of the effect of dip-coating on the   significant enough to compromise the usability of the
            mechanical properties of PA 12 tensile bars        articles. The elongation-to-break remains around 7%, well
            The parts manufactured with PBF processes (HSS and   above the critical threshold of 2%, which would make it
            SLS) generally have  a lower  elongation-at-break  and   unusable.























            Figure 12. Mechanism of formation of reactive oxygen species such as O  and OH from nanoparticles. Adapted from 44
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            Figure 13. Tensile properties of PA 12 control and Mg(OH) -coated PA 12 made by high-speed sintering. Tensile stress-at-break (A), modulus (B), and
                                                  2
            elongation at break (C).
            Abbreviation: PA: Polyamide
            Volume 3 Issue 4 (2024)                         12                             doi: 10.36922/msam.4970
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