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Materials Science in Additive Manufacturing                            Sustainable resin for coral restoration



                                                               covered the whole coral plugs but not the area around
                                                               the coral fragments. One of the hypotheses is that coral
                                                               fragments might release certain chemical compounds or
                                                               signals during their initial growth or attachment phase that
                                                               repel or inhibit the settlement and growth of algae. 53-55  This
                                                               could be a natural defense mechanism of corals to prevent
                                                               algae overgrowth, which is a positive indication.

            Figure 14. Scanning electron microscope images of the printed calcium   At day 25, the purple crustose coralline algae (CCA)
            carbonate-photoinitiated scaffold. The right picture provides a zoomed-in   was  clearly  visible  on  the  surface  of  the  modified  CCP,
            view of the part circumscribed in the black square on the left image.  AESO, and ceramic plugs (Figure 16). CCA plays a crucial
                                                               role in the formation and maintenance of coral reefs. CCA
                                                               deposits calcium carbonate in their cell walls, giving them
                                                               a hard, crusty appearance. They are often found covering
                                                               the surfaces of coral reefs, contributing to reef structural
                                                               integrity, and providing a substrate for coral larvae to
                                                               settle on. 56

                                                                 After 3  months, a notable progression was evident
                                                               as the coral tissue expanded its coverage on the printed
                                                               substrate, as  illustrated  in  Figure  17.  The  growth  was
            Figure 15. Microfragmentation on different coral plugs at day 1 (left)
            and day 20 (right). For both images, the first row showcases the calcium   observed spreading in both dimensions, in two and three
            carbonate-photoinitiated plugs, the second the acrylated epoxidized   dimensions, respectively, indicating successful settlement
            soybean oil plugs, and the third the ceramic plugs.  and adaptation of the corals to the printed substrate.

















            Figure 16. Microfragments on different coral plugs at day 25. From left to right: Acrylated epoxidized soybean oil, calcium carbonate-photoinitiated, and
            ceramic plugs. The purple crustose coralline algae can be seen on the side of the surface.






















            Figure 17. Photo depicting experiment of microfragmentation on calcium carbonate-photoinitiated coral plugs (first row) and ceramic coral plugs (second
            row) on day 90.


            Volume 3 Issue 2 (2024)                         10                             doi: 10.36922/msam.3125
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