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Materials Science in

                                                                 Additive Manufacturing




                                        ORIGINAL RESEARCH ARTICLE
                                        Enhanced strength of A131 steel via

                                        heterostructures induced by laser-directed
                                        energy deposition



                                        Yuchao Bai 1,2,3  , Silu Zhang 1,2,3  , Qi Yan 1,2,3 * ,Cuiling Zhao 1,2,3 * ,
                                        and Jiaming Zhan 4
                                        1 Guangdong Provincial Key Laboratory of Intelligent Morphing Mechanisms and Adaptive Robots,
                                        Harbin Institute of Technology, Shenzhen, Guangdong, China
                                        2 Key University Laboratory of Mechanism and Machine Theory and Intelligent Unmanned Systems
                                        of Guangdong, Harbin Institute of Technology, Shenzhen, Guangdong, China
                                        3 School of Robotics and  Advanced Manufacture, Harbin Institute of  Technology, Shenzhen,
                                        Guangdong, China
                                        4 School of Advanced Manufacturing, Sun Yat-sen University, Shenzhen, Guangdong, China
                                        (This article belongs to the Special Issue: Metallic Additive Manufacturing)




                                        Abstract

                                        The trade-off between strength and plasticity has posed a challenge to the broader
                                        application of conventional metallic structural materials in high-speed, heavy-load,
                                        and extreme service environments. Heterogeneous structure designs could potentially
            *Corresponding authors:
            Qi Yan                      overcome these limitations with their inherent superior combination of strength and
            (galaxy.yanqi@gmail.com)    plasticity. To harness this potential, this study employed a directed energy deposition
            Cuiling Zhao                additive manufacturing (AM) technology to fabricate a novel heterostructure in
            (zhaocuiling@hit.edu.cn)    as-built (AB) A131 steel, consisting of alternating coarse and fine-grain layers along
            Citation: Bai Y, Zhang S, Yan Q,   the building direction. In addition, a heat treatment process was applied to fabricate a
            Zhao C, Zhan J. Enhanced strength   near-homogeneous microstructure, allowing for the investigation of the role of crystal
            of A131 steel via heterostructures
            induced by laser-directed energy   misorientation in tensile anisotropy. Compared to the performance of commercial
            deposition. Mater Sci Add Manuf.   hot-rolled ASTM A131 steel (yield strength [σ ]: 346.5 MPa; ultimate tensile strength
                                                                             YS
            2025;4(3):025220038.        [σ ]: 545.0 MPa), the AB A131 steel achieved significant enhancements of 168.3%
                                         UTS
            doi: 10.36922/MSAM025220038  and 78.0% in σ  and σ , respectively, when maintaining a comparable elongation
                                                    YS
                                                           UTS
            Received: May 27, 2025      of 24.6% along the deposition direction similar to  the ASTM A131 standard.
                                        Comprehensive experimental characterizations, combined with molecular dynamics
            Revised: June 14, 2025
                                        simulations, were conducted to investigate the underlying formation mechanism of
            Accepted: June 16, 2025     the heterostructure and the origins of mechanical anisotropy. It was found that single-
            Published online: July 21, 2025  pass deposition produced three distinct microstructure regions with different grain
                                        sizes owing to dendrite growth. With repeated thermal cycles, these evolved into a
            Copyright: © 2025 Author(s).   layered heterostructure consisting of alternating fine crystals and coarse-columnar
            This is an Open-Access article
            distributed under the terms of the   grains. This heterostructure remarkably contributed to an exceptional improvement
            Creative Commons Attribution   in strength, accompanied by only a minor reduction in plasticity.  These findings
            License, permitting distribution,   present an efficacious avenue for substantially augmenting the mechanical properties
            and reproduction in any medium,
            provided the original work is   of conventional iron-based alloys, offering useful references for overcoming the
            properly cited.             strength-plasticity trade-off in other alloys fabricated by AM.
            Publisher’s Note: AccScience
            Publishing remains neutral with   Keywords: Additive manufacturing; A131 steel; Heterostructure; Mechanical
            regard to jurisdictional claims in
            published maps and institutional   performance; Molecular dynamics
            affiliations.


            Volume 4 Issue 3 (2025)                         1                         doi: 10.36922/MSAM025220038
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