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International Journal of Bioprinting


                                        RESEARCH ARTICLE
                                        PVDF/AgNP/MXene composites-based near-field

                                        electrospun fiber with enhanced piezoelectric
                                        performance for self-powered wearable sensors



                                        Cheng-Tang Pan 1,2† , Karishma Dutt , Amit Kumar , Rahul Kumar ,
                                                                                  3
                                                                                               1
                                                                      1†
                                        Cheng-Hsin Chuang , Yi-Ting Lo , Zhi-Hong Wen , Chien-Shu Wang *,
                                                                                 5
                                                                   4
                                                         3
                                                                                                 4
                                        Shiao-Wei Kuo 2,6,7 *
                                        1 Department of Mechanical and Electro-Mechanical Engineering, National Sun Yat-sen University,
                                        Kaohsiung 80424, Taiwan
                                        2 Institute  of  Advanced Semiconductor Packaging and  Testing, College  of  Semiconductor and
                                        Advanced Technology Research, National Sun Yat-sen University, Kaohsiung 80424, Taiwan
                                        3
                                        Institute of Medical Science and Technology, National Sun Yat-sen University, Kaohsiung 80424,
                                        Taiwan
                                        4 Department of Psychiatry, Kaohsiung Armed Forces General Hospital, Kaohsiung, 80284, Taiwan,
                                        ROC
                                        5 Department of Marine Biotechnology and Resources, National Sun Yat-sen University, Kaohsiung
                                        80424, Taiwan
                                        6 Department of Materials  and Optoelectronic  Science, Center for Functional Polymers and
                                        Supramolecular Materials, National Sun Yat-sen University, Kaohsiung 80424, Taiwan
                                        7 Department of Medicinal and Applied Chemistry, Kaohsiung Medical University, Kaohsiung 807,
            † These authors contributed equally
            to this work.               Taiwan
            *Corresponding author:      (This article belongs to the Special Issue: Near-field Electro spinning and Melt Electrowriting for Biotechnology
            Shiao-Wei Kuo               and Biomedicine)
            (kuosw@faculty.nsysu.edu.tw)
            Citation: Pan C-T, Dutt K, Kumar A,    Abstract
            et al., 2023, PVDF/AgNP/MXene
            composites-based near-field
            electrospun fiber with enhanced   MXenes, as highly electronegative and conductive two-dimensional nanomaterials,
            piezoelectric performance for self-  are extensively studied for their use in sensors and flexible electronics. In this study,
            powered wearable sensors.    near-field electrospinning was used to prepare a new poly(vinylidene difluoride)
            Int J Bioprint, 9(1): 647.
            https://doi.org/10.18063/ijb.v9i1.647   (PVDF)/Ag nanoparticle (AgNP)/MXene composite nanofiber film as a self-powered
                                        flexible human motion-sensing device.  The composite film displayed highly
            Received: June 24, 2022     piezoelectric properties with the presence of MXene. Scanning electron microscopy,
            Accepted: September 11, 2022
            Published Online: November 24,   X-ray diffraction, and Fourier transform infrared spectroscopy revealed that the
            2022                        intercalated MXene in the composite nanofibers was evenly spread out, which not
            Copyright: © 2022 Author(s).   only prevented the aggregation of MXene but also enabled the composite materials
            This is an Open Access article   to form self-reduced AgNPs.  The prepared PVDF/AgNP/MXene fibers displayed
            distributed under the terms of the   exceptional stability and excellent output performance, enabling their use for
            Creative Commons Attribution
            License, permitting distribution   energy harvesting and powering light-emitting diodes. The doping of MXene/AgNPs
            and reproduction in any medium,   increased the electrical conductivity of the PVDF material, improved its piezoelectric
            provided the original work is   properties, and enhanced the piezoelectric constant of PVDF piezoelectric fibers,
            properly cited.
                                        thereby  allowing the production of flexible, sustainable, wearable, and self-powered
            Publisher’s Note: Whioce    electrical devices.
            Publishing remains neutral with
            regard to jurisdictional claims in
            published maps and institutional
            affiliations.               Keywords: Near-field electrospinning; Piezoelectric fibers; Sensing elements;
                                          Conductive fillers; Composite materials





            Volume 9 Issue 1 (2023)                        336                      https://doi.org/10.18063/ijb.v9i1.647
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