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Materials Science in Additive Manufacturing                          3D-printed composite auxetic structures




            A                 B             C                  thermoplastic polymer called CFC PA and continuous
                                                               fiber-reinforced composite into the nozzle. As shown in
                                                               Figure 4, the left nozzle is used for fabricating the plastic
                                                               external shell (Figure 4B) and the right nozzle is used to
                                                               extrude continuous fiber composites (Figure  4D). The
                                                               reinforcing fiber is a 1.5K composite carbon fiber with
                                                               a diameter of 0.36 mm and a tensile strength of 2130 ±
                                                               230 MPa. Smooth PA, CFC PA, and composite carbon
                                                               fiber  were obtained from  Anisoprint . The  mechanical
                                                                                             [32]
                                                               properties of the printing materials are listed in Table 1.
                                                               The printing temperature of both nozzles is 240°C, and the
                                                               building plate temperature is 60°C.

            Figure 1. (A-C) Tree types of auxetic structures.    Figure 5 illustrates the printing layers of the specimen
                                                               during  fabrication.  For  the  composite  specimen
                                                               (Figure  5B), there are 15 layers in total. The height of
                                                               the first layer is 0.2 mm, while the height of other layers
                                                               fabricated with Smooth PA is 0.12 mm. The layer height
                                                               of continuous fiber-reinforced composite is three times
                                                               that of the external shell, i.e., 0.36  mm. It should be
                                                               noted that there are interlaced and overlapping regions
                                                               in the designed fiber path (e.g., Figure 3A and E). The
                                                               3D printer is capable of handling local overlaps of fibers.
                                                               As shown in Figure 4D, the composite extruder presses
                                                               the fiber composites to fill the matrix. The local overlaps
                                                               are compacted for controlling layer height (Figure 4E).
                                                               Due to the high stiffness of fibers and the excessive
                                                               force from the nozzle [33] , the 3D-printed fiber bundles
                                                               cannot build sharp corners, as shown in Figure 4C. The
            Figure 2. Dimensions of the test specimen.         specimens without reinforcing fibers utilize the same path
                                                               pattern for the plastic nozzle but lack the fiber composite
            mechanical properties of composites. As shown in Figure 3,   extruder, thereby transforming the fiber space into a void
            different types of fiber distributions were designed for   (Figure 5A). The 3D-printed test specimens are displayed
            each type of specimen. To better differentiate between the   in  Figure  6. Compared with specimens fabricated by
            staggered fiber paths, the continuous fiber paths, as shown   Smooth PA, there was a minor increase in the weight of
            in  Figure  3, were colored orange or blue. For rotating   the continuous fiber-reinforced composite structures.
            rigid, the first distribution contains fiber paths along the x
            direction and y direction (Figure 3A). In the second design   2.3. Evaluation of mechanical properties
            (Figure 3B), only fibers along the y direction will infill the   Uniaxial tensile tests were performed on the WDW-20M
            structure. The third design (Figure 3C) contains only fibers   universal test machine with a maximum 20 kN load
            along the x direction. The fiber paths in re-entrant FR1   (Figure 7A). The loading speed was set to 5 mm/min. The
            (Figure 3D) are distributed along the y direction, and the   load and displacement data derived from the test machine
            fiber paths in re-entrant FR2 (Figure 3E) are distributed   were used to plot the stress-strain curves. The tensile
            along the x direction. The rhombus FR is designed with   modulus E  was extracted from the linear stage of stress-
                                                                        y
            fiber paths along the y direction.                 strain curve using Equation I:
                                                                      σ
            2.2. Fabrication of specimens                         E =  ε                                   (I)
                                                                   y
            The test specimens were fabricated using the Anisoprint    y
                                                        [32]
            A4 3D printer (Figure 4A). There are two nozzles in the                         F
            printer; the plastic nozzle extrudes Smooth PA, which is a   where σ is the stress calculated by   A   in which A is the
            thermoplastic polymer material filled with chopped carbon   cross-section area. The peak stress of the stress-strain
            fibers, whereas the other nozzle simultaneously feeds   curve is regarded as tensile strength.


            Volume 2 Issue 4 (2023)                         3                       https://doi.org/10.36922/msam.2159
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