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Materials Science in Additive Manufacturing                           Laser DED-produced Ti-6Mn-4Mo alloy



            4. Conclusions                                     Ethics approval and consent to participate

            In this study, Ti-6Mn-4Mo alloy was successfully   Not applicable.
            synthesized by  in  situ alloying of elemental powders
            using  laser  DED  technique.  Both  as-built  and  heat-  Consent for publication
            treated materials were analyzed for resultant density,   Not applicable.
            tensile properties, hardness, microstructure, elemental
            distribution, and corrosion resistance. The key findings are   Availability of data
            summarized in the following:                       The data used in this study have been included in the paper.
            (i)  As-built Ti-6Mn-4Mo consisted mainly of  β phase,
               while  there  were  signs  of  α  phase  presence  in  a   References
               small quantity. In contrast, the heat-treated material
               mostly consisted of α phase with traces of β phase still   1.   Trevisan F, Calignano F, Aversa A,  et al., 2017, Additive
               present. EDS mapping revealed that the distributions   manufacturing of titanium alloys in the biomedical field:
                                                                  Processes, properties  and applications.  J  Appl  Biomater
               of elements were overall uniform.                  Funct Mater, 16: 57–67.
            (ii)  The densities of both as-built and heat-treated
               Ti-6Mn-4Mo were close to the theoretical density for      https://doi.org/10.5301/jabfm.5000371
               this composition, which was calculated by the rule of   2.   Fu W, Liu S, Jiao J,  et al., 2022, Wear resistance and
               mixture. Furthermore, no cracks or major voids were   biocompatibility of Co-Cr dental alloys fabricated with
               detected, while some Mo powder particles failed to   CAST and SLM techniques. Materials, 15: 3263.
               melt completely.                                   https://doi.org/10.3390/ma15093263
            (iii) The difference in corrosion resistance between the   3.   Niinomi M, 2002, Recent metallic materials for biomedical
               as-built and heat-treated materials was insignificant.   applications. Metallurgical Mater Trans A, 33: 477–486.
               However, the corrosion resistance of both conditions
               was lower than the reported performance for        https://doi.org/10.1007/s11661-002-0109-2
               Ti-6Al-4V  alloys  obtained  through  additive  4.   Li Y, Yang C, Zhao H, et al., 2014, New developments of
               manufacturing techniques.                          Ti-based  alloys  for  biomedical  applications.  Materials,
            (iv)  The DED-produced Ti-6Mn-4Mo materials appeared   7: 1709–1800.
               to be hard and brittle. It is possible that the high      https://doi.org/10.3390/ma7031709
               hardness and modulus were caused by the low     5.   Santos P, Niinomi M, Cho K, et al., 2016, Development of
               concentration of alloying elements and the presence   New Ti-Mn-Mo Alloys for Use in Biomedical Applications.
               of ω phase.                                        In: Proceedings of the 13  World Conference on Titanium.
                                                                                     th
            Acknowledgments                                       John Wiley & Sons, Inc., pp. 1741–1745.
                                                               6.   Maitra V, Shi J, Lu C, 2022, Robust prediction and validation
            None.                                                 of as-built density of Ti-6Al-4V parts manufactured via
                                                                  selective laser melting using a machine learning approach.
            Funding                                               J Manuf Processes, 78: 183–201.
            None.                                                 https://doi.org/10.1016/j.jmapro.2022.04.020

            Conflicts of interest                              7.   Kuroda D, Niinomi M, Morinaga M,  et al., 1998, Design
                                                                  and mechanical properties of new β type titanium alloys for
            The authors declare that they have no competing interests.  implant materials. Mater Sci Eng A, 243: 244–249.

            Author contributions                                  https://doi.org/10.1016/S0921-5093(97)00808-3
                                                               8.   Santos PF, Niinomi M, Cho K, et al., 2017, Effects of Mo
            Conceptualization: Jing Shi                           addition on the mechanical properties and microstructures
            Data curation: Roman Savinov                          of Ti-Mn alloys fabricated by metal injection molding for
            Formal analysis: Roman Savinov                        biomedical applications. Mater Trans, 58: 271–279.
            Investigation: Roman Savinov, Yachao Wang, Jing Shi
            Methodology: Yachao Wang, Jing Shi                    https://doi.org/10.2320/matertrans.m2016286
            Supervision: Jing Shi                              9.   Morioka R, Cho K, Yasuda HY, 2018, Effects of Mo addition
            Visualization: Roman Savinov                          on deformation behavior of metastable beta-type  Ti-Mn
            Writing – original draft: Roman Savinov               single crystals. Mater Sci Forum, 941: 1360–1365.
            Writing – review & editing: Yachao Wang, Jing Shi     https://doi.org/10.4028/www.scientific.net/MSF.941.1360


            Volume 2 Issue 4 (2023)                         11                      https://doi.org/10.36922/msam.2180
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