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Materials Science in Additive Manufacturing                          3D-printed composite auxetic structures



            and energy absorbers [8,9] . It has been found that skins ,   The  3D-printed  continuous  fiber-reinforced
                                                        [10]
            ceramics,  graphite, zeolite, metals, and other natural   composite auxetic structures possess the unified
            auxetic materials exhibit natural auxetic behaviors .   advantages of both continuous fibers and auxetic
                                                        [11]
            Inspired by natural architectures, several types of   structures. Given these desirable benefits, Dong  et  al.
            artificial auxetic structures have been designed, which   developed continuous fiber-reinforced auxetic composite
            can be classified into three types: re-entrant type, chiral   structures for reusable energy absorption applications [28] .
            type, and rotating rigid type . With the advancement of   Another  study fabricated continuous fiber-reinforced
                                   [8]
            additive manufacturing, auxetic structures are fabricated   re-entrant  auxetic  honeycomb  structures  through  the
            as mechanical metamaterials endowed with fascinating   3D  printing  technology  by  tailoring  the  printing  path
            physical properties [12-15] .                      to ensure better fiber path continuity [29] , and concluded
              Due to the porosity and deformability, auxetic   that adding continuous fibers led to dramatic increases
            structures generally have lower stiffness and load-  in compressive stiffness, energy absorption, and smaller
            bearing capacity. To enhance the mechanical properties   NPR. As disclosed earlier, the auxetic behaviors come
            of auxetic materials, auxetic composites are developed.   from different types of deformation mechanisms, and
            The auxetic chiral structure can be 3D-printed with   due to the high and anisotropic stiffness/strength of
            thermoplastic polyurethane elastomer (TPU) and     continuous fibers, their addition would not result in
            then filled with polyurethane (PU) foam, producing   consistent performance on different types of auxetic
            a foam-filled chiral structure that is significantly   structures.
            reinforced  in  terms  of  stiffness  and  specific  energy   This study aimed to investigate the mechanical properties
            absorption capacity . A study by Xue et al. [16]  showed   of 3D-printed continuous fiber-reinforced composite
                            [5]
            that the composites fabricated by combining aluminum-  auxetic structures. Auxetic test specimens with different
            based auxetic lattice structure with polymer fillers   topology and fiber path configurations were fabricated
            exhibited higher elastic modulus, compressive strength,   and evaluated for mechanical properties, including tensile
            and energy absorption capacity, as verified in the   modulus, tensile strength, and Poisson’s ratio, using uniaxial
            compressive experiment. Another study showed that the   tensile test. The effect of adding continuous fibers on the
            printed auxetic chiral structures fabricated from high-  properties of the structures is discussed.
            performance  composites  added  with  chopped  carbon
            fibers manifested enhanced tensile modulus, strength,   2. Materials and methods
            and energy absorption [17] .                       To investigate the mechanical properties of continuous
              Continuous fiber-reinforced composites encompass   fiber-reinforced composite auxetic structures, we designed
            several desirable advantages, such as lightweight, high   and fabricated a group of test specimens and evaluated
            strength, and stiffness. They have been widely used in the   their mechanical properties through a uniaxial tensile test.
            fields of automobile, aircraft, and space [18-20] . 3D printing of
            continuous fiber-reinforced composites provides a feasible   2.1. Design of specimens
            avenue to bridge the gap between advanced materials and   Three types of structures are selected as test specimens
            innovative structures. Hou  et al. have demonstrated the   (Figure 1). Two of them are auxetic structures: the rotating
            design and fabrication of a novel corrugated structure and   rigid  and the re-entrant types . The other is a structure
                                                                   [30]
                                                                                        [31]
            discussed the correlations among the process parameters,   with a positive Poisson’s ratio named rhombus. The
            structure parameters, density, fiber content, and final   dimensions of the unit cell of the three specimens are 16 ×
            performance of the printed specimens . Besides that, the   16 mm. The rotation angle of a single square in a rotating
                                          [21]
            manufacture of sandwich structures in different shapes   rigid structure is 15°. The width of rods in re-entrant and
            using a continuous carbon fiber 3D printer has also   rhombus structures is 2 mm.
            been attempted . Considering the requirement on path   Figure 2 displays the dimensions of the test specimen.
                        [22]
            continuity, Liu  et al.  proposed a path-driven design   The test specimen is composed of a 4 × 7 array of unit
                             [23]
            method to generate lattice structures with designable   cells and two holders. To capture a more obvious auxetic
            anisotropy  and close-to-zero  mean  curvatures  for  3D   behavior and shorten the manufacturing cycle, the
            printing of continuous fiber-reinforced composites. In
            addition to improving mechanical properties, accentuating   thickness of specimens was set as 2 mm. The test specimen
            the multi-functional properties of continuous fibers such   was fixed on the test machine through holders, and the
            as sensing , shape morphing, [25,26]  and electromagnetic   uniaxial tensile loads were applied along the y direction.
                    [24]
            interference shielding  provides a new direction for   Due to the property anisotropy of continuous fibers,
                              [27]
            developing smart structures.                       the distribution of fiber paths has a great impact on the

            Volume 2 Issue 4 (2023)                         2                       https://doi.org/10.36922/msam.2159
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