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Materials Science in Additive Manufacturing                                   Functional materials for AM



            robots capable of achieving complex behaviors through   resulting in macroscopic deformation and exhibiting
            the  use  of  3D-printed  magnetically  responsive soft   intricate behavior. 41-43
            materials (Table  2). Embedded magnetic filler particles   A method has been developed to program complex
            generate internal stress as they attempt to align with   non-uniform magnetic domain patterns using permanent
            the magnetic field under external magnetic influence,   magnets or electromagnets on hard magnetic particles

            A                                 B                               C














            Figure  3.  Comparison of magnetization characteristics under magnetic field. (A) Hard magnetic materials. (B) Soft magnetic materials. (C)
            Superparamagnetic materials.


            Table 2. Comparison of materials and fabrication methods for magnetically responsive soft robots
            3D printing method   Material composition     Description                                References
            Material extrusion (DIW)  NdFeB microparticles+thermoplastic  NdFeB-SIS composite ink is developed to provide high   41
                                 elastomers (styrene-isoprene block   elasticity (>1000%), and an origami-inspired printing method is
                                 copolymers)              introduced for reprogramming.
            Material extrusion (DIW)  NdFeB microparticles+silicone   The evolutionary algorithm-guided voxel encoding is proposed   42
                                 elastomers (SE1700 and Ecoflex   to design tailored magnetic density and direction, leading to
                                 00-30 Part B)            functional biomimetic soft robots and expanded applications.
            Material extrusion (DIW)  NdFeB microparticles+silicone   A new 3D printing technology is proposed for   44
                                 elastomers (SE1700 and Ecoflex   shape-programmable soft materials utilizing magnetic fields for
                                 00-30 Part B)            untethered actuation and delivering potential for biomedical
                                                          devices, and soft robotics via customized domain patterns and
                                                          magnetization strength.
            Material extrusion (DIW)  NdFeB microparticles+silicone   A 4D printing method utilizing an origami-based magnetization   43
                                 elastomers (Sylgard 184)  technique is proposed. This method enables the fabrication of
                                                          complex objects with the ability to reprogram their magnetization.
                                                          Bionic hands serve as an example of this capability.
            Material extrusion (DIW)  NdFeB microparticles+thermoplastic  A continuum soft robot with omnidirectional steering   45
                                 elastomers (thermoplastic urethane)  capabilities, miniaturized ferromagnetic domains, and hydrogel
                                 NdFeB microparticles+silicone   skin for navigation in complex environments and steerable laser
                                 elastomers (Sylgard 184)  delivery was presented for minimally invasive robotics surgery.
            Material extrusion (DIW)  NdFeB microparticles+silicone   A coaxial printing method for creating soft-magnetic-electrical   47
                                 elastomers (SE 1700)     fibers is presented, enabling hybrid functions issues in soft
                                                          robotics and biomedical applications, demonstrated by
                                                          catheter-based electro-ablation, somatosensory gripper.
            Vat photopolymerization   NdFeB microparticles+photocurable   A UV lithography-based method is presented for patterning   49
            (DLP)                elastomers               magnetic particles in elastomer matrices, enabling custom 3D
                                                          magnetization profiles for higher-order microrobots, leading to
                                                          locomotion with multi-arm grasping and multi-legged crawling.
            Vat photopolymerization   Fe O  nanoparticles+photocurable   A comprehensive solution for designing and fabricating a 3D   50
                                  3
                                    4
            (CLIP)               elastomers               micro-robotic gripper using a high-resolution CLIP process for
                                                          untethered operation in both dry and aqueous environments has
                                                          been presented, resulting in a monolithic gripper design.
            Abbreviations: CLIP: Continuous liquid interface production; DIW: Direct ink writing; DLP: Digital light processing; NdFeB: Neodymium magnet.

            Volume 3 Issue 2 (2024)                         6                              doi: 10.36922/msam.3323
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