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Materials Science in Additive Manufacturing                     Wide-angle broadband MMA with CB-CIP/PLA



            resistance loss (carbon black [CB],   graphene,  carbon   MMA has a broadband absorption of 6.8 – 20.8 GHz.
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            fiber,  carbon nanotubes ) and magnetic loss (ferrite, 10,11    These studies achieved the best absorption performance
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            metal powder 12,13 ). However, broadening the absorption   by using different materials and adjusting geometric
            bandwidth greatly reduces the reflection loss (RL) and   parameters, but these absorbing structures still struggled
            absorption performance. Metamaterial absorbers (MMA)   to achieve over 90% absorption in the frequency range of
            provide a solution to this problem. An MMA is an artificial   2 – 18 GHz.
            structure composed of a periodic array of unit structures   In comparison to the conventional preparation process,
            (subwavelength scale) with adjustable electromagnetic   3D printing technology is suitable for fabricating a complex
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            characteristics.  Compared with the conventional wave-  microwave-absorbing structure  and  features  advantages
            absorbing coating, the electromagnetic properties of MMA   such as high efficiency and material utilization. 30-32
            are not just dependent on the material properties, but also   A  variety  of  3D  printing  processes  have  been  used  to
            the unit structure.  Through macroscale (structural) and   prepare composite MMAs, including stereolithography,
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            microscale (material) control, better impedance-matching   selective laser sintering,  direct ink writing,  digital light
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            performance can be achieved, effectively increasing the   processing,  and fused filament fabrication (FFF). 23,32,37
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            absorption bandwidth and angle. 16                 Among them, the FFF process is the most widely used
              Recent designs  of the  MMA  have been  proposed  to   because of the low cost of materials and equipment.
            improve the  microwave absorption performance. 17-19    In this study, a complex composite MMA was proposed
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            Chen  et al.  proposed a pyramidal absorber, which can   to achieve excellent absorption properties and fabricated
            achieve over 90% absorption in the frequency range of   using FFF 3D printing technology. The MMA material
            5.3 – 18 GHz due to both the material properties and the   consists of CB (for resistance loss), carbonyl iron powder
            synergistic effect of its geometry. Pei et al.  designed and   (CIP; for magnetic loss), and polylactic acid (PLA; as the
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            fabricated a gradient honeycomb absorber, which has an   matrix). The MMA structures were designed and optimized
            excellent absorption property at 8 – 12 GHz. Feng et al.    using electromagnetic simulation. The reflectivity of
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            designed a truncated pyramidal metamaterial and studied   printed MMA structures was experimentally measured to
            the impact of geometric parameters and array period on   verify the simulation results.
            its absorption property. The absorption performance of the
            metamaterial can be improved by changing the geometric   2. Methods
            parameters of the structure while maintaining the inherent
            electromagnetic characteristics of the material. The peak   2.1. Design of MMA structure and electromagnetic
            RL of the optimized structure reached −22.5 dB, and the   simulation
            corresponding effective absorption bandwidth (EAB) was   The MMA structure is composed of an array of stepped
            up to 9 GHz. Yin et al.  and Tian et al.  designed and   square  hole  (SSH)  units  as  schematically  presented  in
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            fabricated a multilayer metamaterial microwave absorption   Figure  1. This design was inspired by the pyramidal
            structure based on the impedance gradient change of   absorber with stepped projection.  The SSH unit can
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            woodpile structure. The impedance matching coefficient   be seen as the remaining part of a cube subjected to
            varied  with  the  pile  width.  The  optimized  bandwidth   geometric Boolean operations with a pyramid structure.
            was 4.5 – 40 GHz and the peak RL was −35 dB. Begaud   The geometric parameters of the SSH structure include the
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            et  al.   designed  a  multilayer  structure  that  can  reach   maximum hole radius (R), wall thickness (W), and height
            −10  dB absorption bandwidth in the frequency range   (H, H , and H ). An electromagnetic model was developed
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            of 3.7 – 17.5 GHz. Wang et al.  proposed a wide-angle   in CST Studio Suite software (Dassault Systèmes, France)
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            broadband  absorption  based  on  both  indium  tin  oxide   to simulate the microwave absorption performance of
            and metapyramid geometry at 8 – 12 GHz. Xu  et al.    the structure. Finer tetrahedral meshes were used in the
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            designed a kirigami-inspired transformable metamaterial   simulation to ensure convergence and data validity. The
            for adaptive invisibility, which provides a new avenue   electromagnetic properties of the CB-CIP/PLA composite
            toward multifunctional smart devices. Xu  et  al.    were input into the model. The parameter sweep method
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            designed a triple-band absorber enhanced by a planar   was used for the optimization of geometric parameters.
            2D artificial metamaterial transmission line concept. The   The sweep range for different parameters is listed in
            absorber featured near-unity absorption for a wide range   Table 1. The sweep interval is 2 mm for R, H, H  and H  and
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                                                                                                   1,
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            of incident angles and polarization states. Wang et al.    0.2 mm for W. The effect of geometric parameters on the
            proposed a thin broadband multilayer MMA, using the   RL of the MMA was compared, and the optimal geometric
            concepts of multimode-assisted strategy and impedance-  parameters were determined based on factors such as peak
            gradient theory to widen the bandwidth. The designed   value and EAB. The effect of polarization and incident
            Volume 3 Issue 3 (2024)                         2                              doi: 10.36922/msam.4158
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