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Designs and Applications of EHD 3D Printing
           to employ a highly viscous liquid . It is used in the   droplets is slow on the insulating substrates, the residual
                                         [1]
           field  of  micro- or  nano-manufacturing  for  patterning   charge of droplets deposited onto a substrate will change
           of a large class of materials  on a variety of substrates   the electrostatic field distribution and may interrupt the
           without adversely affecting the chemical properties of the   subsequent printing behavior . Park et al. used a sinusoidal
                                                                                      [8]
                                                                                                         [8]
           deposited materials. This paper is organized as follows.   ac voltage to switch the charge polarity of droplets  and
           We describe different types of EHD printing machines   charges in the subsequent droplet to neutralize charges
           designed on the basis of fundamental EHD mechanisms.   in the previous droplet. A visualization system includes a
           The  ensuing  section  discusses about  the  application  of   high-speed charge-coupled device camera, a microscopic
           EHD inkjet printing in different fields of research.  zoom  lens  system,  and  an  illumination  source.  Since
                                                               the timescale  for the most relevant  EHD phenomena
           2. EHD Inkjet Printing Machines and Control         is very short (less than a microsecond), a conventional
                                                               continuous-illumination  source  will  cause  blurring
           An EHD inkjet  printing  system  usually  consists  of a   images by overexposure of jet motion. Thus, a high-speed
           fluid  supply  system,  linear/rotary  motorized  or  manual   shutter  system  or  a  short  duration  flash  with  an  open
           positioners, a high voltage power supply, and visualizing   shutter is suitable  for  high-speed  events.  The  external
           and imaging devices . The fluid supply system delivers   disturbances, such as vibration coming from the building,
                            [2]
           liquid ink through a pipeline to the tip of the nozzle at the   may be damped by vibrational isolation platform. These
           desired flow rate. The supply system can be a syringe or   attributes often lead to demands for careful control and
           vacuum pump  or a liquid reservoir with a constant liquid   optimization for each ink material. Table 1 summarizes
                      [3]
           height [4,5] .  The dispensing nozzle (usually made from   the optional devices for each subsystem of EHD print.
           stainless steel) is compatible with interchangeable syringe   Park demonstrated that a nozzle with a diameter of
           and can be purchased from commercial companies. The   50 µm can create dot diameter not <20 µm in graphic arts.
           tiny size of nozzle (smaller than 50 µm) can be fabricated   In addition, they developed an EHD inkjet printing system
           by pulling glass pipettes or borosilicate capillaries and the   as shown in Figure 1a and a droplet with submicrometer size
           tip of nozzle is coated by a thin layer of metal. To prevent   was able to be produced by a microcapillary with a diameter
           wetting of the ink and obtain a large contacting angle at   from 0.3 to 30 µm . The resulting high resolution is partially
                                                                             [9]
           the  nozzle  outlet,  metal  nozzles  are  usually  processed   attributed to a fine nozzle with sharp tips. Another reason is
           by chemical  agents.  The  nozzle  is grounded while  a   that small distance between nozzle and substrate shown in
           high negative potential  is applied to the substrate and   Figure 1b can minimize lateral variations in the placement
           this prevents charge accumulation and potential  shock   of droplets. Furthermore, breakup occurring in electrospray
           hazards  during  the  operation  of the  pumping  system .   can be avoided at such short distance , and a sharp corner is
                                                         [6]
                                                                                            [5]
           The gap between the nozzle tip and the substrate, known   also benefited from a small gap. Fluid is propelled through a
           as standoff height, is critical for stable printing. Thus, it   glass capillary by a syringe pump. A high-speed camera with
           is necessary to use a high precision motorized stage to   66,000 frames per second was used to observe the dynamics
           adjust standoff height. A high DC voltage power source   of EHD jetting, and both pulsating and stable jet modes are
           is employed to produce a strong electric field to deform   captured by imaging devices. Park et al. used a solution of
           the liquid meniscus, and a function or pulse generator is   a conducting polymer ink to electrohydrodynamically print
           used  to  facilitate  drop-on-demand  printing.  To  supply   high-resolution patterns with 10 µm droplet diameter , as
                                                                                                          [9]
           voltage and ink material to multiple nozzles separately, a   shown in Figure 1c. Figure 1d shows EHD printing results
           voltage distributor and a multichannel syringe pump are   of silicon nanoparticles and single crystal Si rods dispersed
           necessary . Since the decay rate of residual charges on   in 1-octanol .
                   [7]
                                                                        [9]
           Table 1. Functions of each working device in different EHD printing platforms
           Names of EHD printing    Optional devices           Function
           subsystems
           Fluid supply             Syringe pump/vacuum pump/liquid   Delivering ink to the tip of printing nozzle
                                    reservoir, pipeline and connector
           Positioner               Linear/rotary motorized positioner/  Transmitting  nozzle  to  printing  position  accurately;  adjusting  distance
                                    manual positioner          between two electrodes
           Power supply             High voltage DC/AC power supply    Providing strong electric field to produce stable cone-jet
                                    (up to 10 kV)
           Visualizing and imaging device  High-speed CCD camera, Microscopic   Observing deformation of cone and high-speed emission of droplet
                                    zoom lens, LED light
           Vibration isolation platform  Mechanical vibration isolation platform/ Preventing vibration from effecting printing results
                                    optical tables

           2                           International Journal of Bioprinting (2019)–Volume 5, Issue 1
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