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Zheng, et al.
                         A                       B                       C













                         D                       E                       F













                         G












           Figure 2. Micromorphology of Ag@PMoS . (A) TEM images of MoS , (B-F) TEM images of Ag@PMoS . (G) SEM images and EDS
                                          2
                                                               2
                                                                                         2
           analyze of Ag@PMoS .
                           2
                                                               performed by XPS. As shown in Figure 3B, the C, N, O,
                                                               Mo, and Ag elements were detected in Ag@PMoS , in
                                                                                                           2
                                                               which N and C were assigned to polydopamine. Clearly,
                                                               the spectrum of Ag@PMoS  appeared several new peaks
                                                                                      2
                                                               was occurred at 375 – 385 and 578 – 613 eV compared
                                                               to PMoS  and MoS , which were belong to Ag 3d and Ag
                                                                      2
                                                                               2
                                                               3p peaks of metallic Ag, respectively. Figure 3B1 shows
                                                               that  at  368.1eV  and  374.0eV, Ag3d  nuclear  horizontal
                                                               spectrum can be divided into two peaks corresponding to
                                                               Ag3d5/2 and Ag3d3/2 of metallic Ag, respectively . As
                                                                                                         [38]
                                                               can be seen from Figure 3B2, the peak relative strength
                                                               of Ag@PMoS   at  about  298  eV  is  significantly  higher
                                                                           2
                                                               than  MoS  and PMoS ,  which  can  be  attributed  to  the
                                                                       2
                                                                                  2
                                                               C=O band of PDA. It can be inferred that the Ag could
                                                                                                         +
                                                               oxidize the -C-OH of polydopamine to –C=O, and the
                                                               metallic Ag can be immobilized on the surface of PMoS 2
                                                               by the structure of quinone .
                                                                                     [39]
           Figure 3. Characterization of Ag@PMoS . XRD (A) and XPS (B)
                                         2
           spectra  of MoS ,  PMoS , and Ag@PMoS .  (B1)  XPS  for Ag3d   3.3. Microstructure and photothermal
                             2
                      2
                                          2
           orbits of metallic Ag@PMoS . (B2) C1s for the samples of MoS ,   performance of scaffolds
                                                          2
                                2
           PMoS ,and Ag@PMoS .
               2            2
                                                               The  digital  photos  of  PGA,  MoS /PGA,  PMoS /PGA,
                                                                                                         2
                                                                                            2
           respectively .  The surface elemental  configurations   and  Ag@PMoS /PGA  scaffolds  fabricated  by  SLS
                     [37]
                                                                             2
           of MoS   NSs,  PMoS NSs,  and Ag@PMoS NSs were      technology  are shown in  Figure  4A-D,  respectively.
                             2
                                                 2
                 2
                                       International Journal of Bioprinting (2022)–Volume 8, Issue 3       115
            Please cite this article as: Zheng L, Zhong Y, He T, et al., 2022, A Codispersed Nanosystem of Silver-anchored MoS  Enhances Antibacterial
                                                                                            2
            and Antitumor Properties of Selective Laser Sintered Scaffolds, Int J Bioprint, 8(3):0025. http://doi.org/10.18063/ijb.v8i3.0025
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