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Materials Science in Additive Manufacturing                    Crack-free AA7075 with Zr modification via LPBF


              Figure  11  displays the morphology of cracks in   Data curation: Wenhui Yu, Xuhui Zhang, Yetao Sun
            AA7075  samples  fabricated  at  VED  82  J/mm   without   Formal analysis: Wenhui Yu, Zhen Xiao, Xuhui Zhang,
                                                  3
            and  with  1  w.t.%  Zr  addition,  respectively.  The  crack  in   Yongling Wu, Hongyu Zheng
            Figure 11A is wide and smooth-edged along the building
            direction, while the one in Figure 11B is curved, passing   Funding acquisition: Wenhui Yu, Zhen Xiao, Hongyu
            through the intergranular area. The corresponding EDS   Zheng
            line scans display the elemental distribution of silicon   Investigation: Wenhui Yu, Xuhui Zhang, Yetao Sun
            near the cracks. Concentration of silicon detected near the
            cracks indicates that this minor element plays a significant   Methodology: Wenhui Yu, Zhen Xiao, Xuhui Zhang, Yetao
            role in increasing the susceptibility to cracking, consistent   Sun, Peng Xue, Shuai Tan, Yongling Wu, Hongyu Zheng
            with the literature . In Zr-modified parts, silicon would   Project administration: Wenhui Yu, Zhen Xiao, Peng Xue,
                          [42]
                                                                  Shuai Tan, Yongling Wu, Hongyu Zheng
            still segregate  to the  grain  boundaries  and  may weaken   Resources: Xuhui Zhang, Yetao Sun
            the crack resistance. However, the distribution of silicon
            is more homogenous as fine grains result in more grain   Supervision: Wenhui Yu, Zhen Xiao, Peng Xue, Shuai Tan,
            boundaries. Therefore, the effects of silicon on cracks are   Yongling Wu, Hongyu Zheng
            suppressed.                                        Validation: Wenhui Yu, Zhen Xiao, Yongling Wu, Hongyu
                                                                  Zheng
            4. Conclusion                                      Visualization: Wenhui Yu, Xuhui Zhang
            Crack-free AA7075 printed parts were obtained with   Writing – original draft: Wenhui Yu
            elemental Zr addition. Fine equiaxed grains tend to   Writing – review & editing: Wenhui Yu, Zhen Xiao, Xuhui
            form  with  VED above 76  J/mm .  Crack-free  AA7075   Zhang, Yongling Wu, Hongyu Zheng
                                        3
            components were obtained with VED above 82 J/mm .
                                                         3
            The formation of fine equiaxed grains can be attributed   References
            to the Al Zr (the nuclei) and the limited grain growth.
                   3
            The formation of dendritic skeleton accompanied by   1.   Zhang D,  Qiu D,  Gibson MA, et al., 2019,  Additive
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            Acknowledgments                                       https://doi.org/10.1080/17452759.2021.1928520
                                                               3.   Sing SL, Huang S, Goh GD, et al., 2021, Emerging metallic
            The authors express their gratitude to Dr. Wuhong Xin and   systems for additive manufacturing:  In-situ alloying and
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            University of Technology, for their assistance in the   Mater Sci, 119: 100795.
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                                                                  https://doi.org/10.1016/j.pmatsci.2021.100795
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            This work was supported by the financial support from   Int J Bioprinting, 8: 501.
            China Postdoctoral Science Foundation (grant numbers
            2020M672131, 2021M690493), and the Shandong Natural      http://dx.doi.org/10.18063/ijb.v8i1.501
            Science Foundation (grant number ZR2020QE030).     5.   Zhang Y, Attarilar S, Wang L, et al., 2021, A review on design and
                                                                  mechanical properties of additively manufactured NiTi implants
            Conflict of interest                                  for orthopedic applications. Int J Bioprinting, 7: 340–340.
            No potential conflict of interest was reported by the      http://dx.doi.org/10.18063/ijb.v7i2.340
            authors.                                           6.   Gu D, Ma C, Dai D, et al., 2021, Additively manufacturing-
                                                                  enabled hierarchical NiTi-based shape memory alloys
            Author contributions                                  with high strength and toughness.  Virtual Phys Prototyp,

            Conceptualization: Wenhui Yu, Zhen Xiao, Xuhui Zhang,   16(Suppl 1): S19–S38.
               Yongling Wu, Hongyu Zheng                          https://doi.org/10.1080/17452759.2021.1892389


            Volume 1 Issue 1 (2022)                         9                      https://doi.org/10.18063/msam.v1i1.4
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