Page 100 - EER-2-1
P. 100

Explora: Environment
            and Resource                                                                    Artificial neural networks



            3.3. Electrothermal model                            The thermal aspect of the model incorporates

            3.3.1. Principle of the electrothermal model       thermodynamic equations specific to cylindrical cells.
                                                               It assumes a single temperature point, where heat is
            This study employed a one-dimensional electrothermal   generated at a particular location on the cell’s surface,
            model, utilizing a  semi-empirical  approach within the   defined by its specific heat capacity and mass. Heat is
            MATLAB/Simulink® 2024 platform. The model is designed   then dissipated from the cell’s surface to the surrounding
            to simulate the electrical and thermal behavior of the   environment. A heat balance equation at the cell surface
            battery cell through two main modules: the electrical and   is applied to model the thermal exchange between the
            thermal  components.  The  electrical  module  determines   cell and the ambient environment, as described by the
            the  SoC  by  analyzing  electrical  parameters,  while  the   following thermodynamic equations: 53
            thermal module estimates the cell’s temperature using heat
            generation equations.                               dU cell                   dT 
                                                                           t
                                                                                      mCp.
                                                                                  t
                                                                        gen
              The electrical model (Figure 6) is based on the second-    dt  = Q () − Q () = .  dt  
                                                                                loss
                                                               
                                                                                             
            order Thevenin model, 49,50  consisting of a voltage source     Q  = R ( .  I ) 2           (IV)
                                                                                             
                                                               
            in series with two parallel RC networks and an ohmic     Q  = = Q  gen = h  int S .  batt .( T  −T  )  
            resistor. According to the ECM, the output voltage of the     loss  conv  conv  area  cell  amb  
                                                                                             
            Li-ion battery cell is calculated as the voltage drop across                    
                                                               
            the OCV, the ohmic resistance (R ), the concentration
                                         0
            polarization  resistance  (R C   circuit),  and  the  activation   where  U , the internal energy, is the total energy
                                                                         cell
                                 1
                                   1
            polarization resistance (R C  circuit). The resulting output   contained by a thermodynamic system (J);  Q  is the
                                                                                                      gen
                                2
                                  2
            voltage is then computed using the following equation: 7,13  generating heating rate (W) in the corresponding element;
                                                               and  Q  is the heat losses of the corresponding element
              V  = OCV – R I  – R I – R I  (II)                     loss
                cell      1 1  2 2   0 batt                    (W). C  is the specific heat of the cell (kJ/kg.K) and m is the
                                                                    p
              where  I batt  is the flowing current in the battery (A).   mass of the cell (kg). The thermal model operates under
            Thereafter,  the  SoC  is  determined  by  the  Coulomb-  the following assumptions:
            counting method and is defined in: 51,52
                                                                     A
                        1
            SoCSoC=  0  −  C init  ∫ I batt dt         (III)
              where SoC  represents the initial SoC of the cell. C
                       0
                                                         init
            is defined as the initial capacity (Ah), which is assumed
            to be dependent on temperature and influenced by the
            applied current and degradation. In Equation II, the OCV
            was directly obtained from the OCV test, as outlined in
            Section 2.2. The resistances, which vary with temperature,
            SoC, and aging, were determined using a parameter
            extraction algorithm. Based on the HPPC test results, a   B
            fitting algorithm within Batalyse was employed to match
            simulation data with experimental results, allowing for
            the extraction of individual parameters. These extracted
            parameters were then mapped into lookup tables within
            the MATLAB/Simulink® environment.





                                                               Figure  7.  (A) Electrical validation  using the WLTC. (B) Thermal
                                                               validation using the high-current test.
            Figure 6. The schematic of the second-order Thévenin model 55  Abbreviation: WLTC: Worldwide harmonized light vehicles test cycle.


            Volume 2 Issue 1 (2025)                         7                                doi: 10.36922/eer.7228
   95   96   97   98   99   100   101   102   103   104   105