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Engineering Science in

                                                                 Additive Manufacturing




                                        ORIGINAL RESEARCH ARTICLE
                                        Effect of electroshock treatment on

                                        microstructure evolution of Ti-6Al-4V/Cu-Cr-Zr
                                        interface fabricated by laser melting deposition



                                        Shiqiang Xie 1,2†  , Changlin Huang 1,2†  , Jiawei Gong 1,2  , Pei Wang 1,2  ,
                                               1,2
                                        Yan Wen * , and Lechun Xie *
                                                                  1,2
                                        1 State Key Laboratory of Light Superalloys, Wuhan University of Technology, Wuhan, Hubei, China
                                        2 Hubei Key Laboratory of Advanced Technology for Automotive Components, Wuhan University of
                                        Technology, Wuhan, Hubei, China



                                        Abstract

                                        This study aims to examine the effect of electroshock treatment (EST) on Ti-6Al-4V/
                                        Cu-Cr-Zr manufactured by laser melting deposition and explore the microstructure
            † These authors contributed equally   and mechanical properties to investigate the microstructure evolution of copper-
            to this work.               based rail composite materials under high-energy-density currents.  The results
            *Corresponding authors:     indicated  that  EST  could  promote  atomic  diffusion,  enabling  rapid  preferential
            Yan Wen                     growth of TiCu in the metallurgical bonding zone. An increase of the current density
            (gubi2008@whut.edu.cn)
            Lechun Xie                  promoted the nucleation of the primary Ti Cu phase induced by the thermal effect of
                                                                          2
            (xielechun@whut.edu.cn)     EST, which led to Cu solute enrichment and composition undercooling. Moreover, EST
                                        significantly improved nucleation rate and grain boundary migration. The average β
            Citation: Xie S, Huang C, Gong J,
            Wang P, Wen Y, and Xie L.   grain size of the EST-1 sample increased from 2.83 μm to 3.62 μm, approximately,
            Effect of electroshock treatment   while the typical basic texture of EST-1 was enhanced. In EST-1, the shear strength
            on microstructure evolution of   of Ti-6Al-4V/Cu-Cr-Zr was 132 MPa, which was 65% higher than that of the original
            Ti-6Al-4V/Cu-Cr-Zr interface
            fabricated by laser melting   Ti-6Al-4V/Cu-Cr-Zr composite. The improvement in shear strength can be attributed
            deposition. Eng Sci Add Manuf.   to intergranular nano-precipitation and the improved wettability of  Ti-6Al-4V/
            2025;1(4):025430030.        Cu-Cr-Zr. This work provides valuable insights into the preparation of high-value,
            doi: 10.36922/ESAM025430030
                                        high-performance Cu-based composites.
            Received: October 21, 2025
            1st revised: November 6, 2025  Keywords: Electroshock treatment; Ti-6Al-4V/Cu-Cr-Zr interface; Microstructure
            2nd revised: November 11, 2025  evolution; Mechanical properties
            Accepted: November 12, 2025
            Published online: November 28,
            2025                        1. Introduction
            Copyright: © 2025 Author(s).
            This is an Open-Access article   Maintaining high electrical conductivity of copper alloys while increasing surface
            distributed under the terms of the   hardness, heat resistance, and wear resistance can increase the service life of copper
            Creative Commons Attribution   components.  At present, advanced surface strengthening techniques are widely
                                                  1-5
            License, permitting distribution,
            and reproduction in any medium,   employed in the preparation of reinforced layers on copper alloy surfaces to enhance
            provided the original work is   their surface properties.  Laser melting deposition (LMD) is an advanced surface
                                                            6-8
            properly cited.             treatment technology, marked by high deposition efficiency, high surface accuracy, and
            Publisher’s Note: AccScience   a small heat-affected zone of the substrate.  Titanium alloys show characteristics, such
                                                                          9
            Publishing remains neutral with   as high hardness, high temperature resistance, and corrosion resistance. As a coating,
            regard to jurisdictional claims in
            published maps and institutional   it can significantly improve the surface performance of copper alloys. 10-12  In addition,
            affiliations.               Ti-6Al-4V has high strength and low electrical resistance, which can enhance the

            Volume 1 Issue 4 (2025)                         1                          doi: 10.36922/ESAM025430030
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